Anodic polarization curves were also determined for the steel, together with those for ni, cr and fe. Hastelloy c276 has minor corrosion rates in reducing and oxidizing conditions. When the use of such a material cannot be avoided, and where there is danger of transgranular stress corrosion cracking, the use of higher alloy materials such as stabilized incoloys or ferritic stainless steel such as type 444 18 cr2 mo, should be considered. Stress corrosion cracking can be either intergranular along the grain boundaries. Stress corrosion cracking of 316 stainless steel in caustic. Caustic embrittlement or stress corrosion cracking in caustic environment is another serious problem in austenitic stainless steels and causes many explosions and other. Stress corrosion cracking of stainless steels in high temperature caustic solutions. Corrosion behaviour of type 316l stainless steel in hot. The corrosion of stainless steel in hot caustic environment has been the subject of a number of investigations, typically with a focus on kraft pulping liquors 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11. The environments used were deoxygenated 50% naoh solution at 316 and 371 c 600 and 700 f, deoxygenated 10% naoh solution at 316 c and atmospheric boiling 149 c 300 f 50% naoh. The area of risk in sodium hydroxide is shown on the iso corrosion diagram by the area bounded by a green line. This due to high concentration of the caustic soda added to the boiler water to control ph ph 9. Corrosion of this type has been extensively studied and affects almost all metal alloys, including the austenitic grades of stainless steel used in brewing.
The aggressive media to passive layer of stainless steels are chlorides, caustic, and polythionic acid. Other higher nickel stainless alloys like alloy 20, 800 and 825 also resist caustic corrosion and caustic cracking better than the 300 series stainless steels. In many ways, caustic scc of stainless steel represents a forgotten phenomenon, since it was researched, studied and quantified in the 60s and 70s. Stress corrosion cracking of stainless steels in high temperature. Stainless steels are more resistant to general corrosion compared with carbon steel. Mar 04, 2019 caustic corrosion can lead to pitting and other localized corrosion, as they tend to form cathode films that concentrate corrosion in susceptible anode areas. Caustic stress corrosion cracking, also referred to as caustic embrittlement, is a form of degradation that is caused when a component operates in a caustic environment. Deaeration increased the corrosion rate of type 316l stainless steel in hot caustic naoh environment, but exposure to 30 wt% naoh at rt showed the opposite trend. Then, the stress corrosion cracking mechanism for various materials in conditions that are susceptible is discussed in detail. Caustic stress corrosion cracking scc experiments have been conducted on type 304, 304l, 316, 316l, and uss 18182 stainless steels. Webcorr provides corrosion consultancy services, corrosion expert witness and corrosion short courses for inhouse training, online and distance learning. Grades 2205 and 2906 are reported to have useful caustic cracking resistance. It is used in metal degreasing and cleaning processes in a wide range of industry applications.
Abstract austenitic stainless steels are known to be susceptible to caustic stress corrosion cracking scc above approximately 121c. Mild steels steels with low carbon and low alloy content and stainless. The useful safe limit of carbon steel is approximately 150 o f65 o c, both with regard to caustic stress corrosion cracking cscc and corrosion. Most notably, pitting and cracking in this instance had initiated andor. It was later known as stress corrosion cracking which is in turn replaced by caustic cracking. Aug 01, 2018 caustic cracking is a form of stress corrosion cracking most frequently encountered in carbon steels or ironchromiumnickel alloys that are exposed to concentrated hydroxide solutions at temperatures of 482f 250c. Effect of heat treatment on corrosion and stress corrosion. Chloride induced cracking of stainless steels, caustic cracking of plain carbon steels, and ammonia damage to copper alloys are typical examples of this problem. Duplex stainless steels dss with roughly equal amount of austenite and ferrite phases are being used in industries such as petrochemical, nuclear, pulp and. Webcorr provides corrosion consultancy services, corrosion expert witness and corrosion. These alloys can be candidates for service in caustic exposure when corrosion from cooling waters is a concern. Although no stainless steel grade is totally immune to chloride scc, the relative resistance of stainless. Three different mechanisms involved in stress corrosion. Stress corrosion cracking is a general term describing stressed alloy failures appearing as cracks in the stainless steel that occur in corrosive environments.
S32010 duplex stainless steel pipe resistant to stress. Effect of heat treatment on corrosion and stress corrosion cracking of s32205 duplex stainless steel in caustic solution article in metallurgical and materials transactions a 406. Stress corrosion cracking scc is a progressive fracturing that occurs in metals as a result of the combined influence of tensile stress and a corrosive environment. Abstract caustic stress corrosion cracking scc experiments have been conducted on type 304, 304l, 316, 316l, and uss 18182 stainless steels. However, when sulfides are present in caustic solutions the scc of austenitic stainless steels has been reported to occur at lower temperatures. However, when sulfides are present in caustic solutions the scc of austenitic stainless steels has been reported to occur at. Stress corrosion cracking scc stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. The higher alloyed duplex stainless steel alloys, ones with significant molybdenum and nitrogen additions, can be superior to 316 ss in caustic environments. The mechanism is similar to that of chloride stress corrosion. Although stress corrosion cracking of duplex stainless steels in chloride solution has been investigated and well documented in the literature, scc mechanisms. China s32010 duplex stainless steel pipe resistant to stress corrosion cracking, find details about china austenitic and ferritic stainless steel, higher plasticity and toughness from s32010 duplex stainless steel pipe resistant to stress corrosion cracking shanghai bozhong metal group co. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. However, many dss grades have been reported to undergo corrosion and stress corrosion cracking in some aggressive environments such as chlorides and sulfidecontaining caustic solutions. Caustic embrittlement was first used to describe the cracking of riveted mild steel boiler plates due to local deposition of concentrated hydroxide at temperatures of 200 to 250 o c 400 to 480 o f.
Ricker, national institute of standards and technology stress corrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Stress corrosion cracking of duplex stainless steels in. Explains caustic embrittlement, season cracking, hydrogen embrittlement. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Stress corrosion cracking scc of type 316 stainless steel was studied in hot 92c solutions of 3. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that. Schematic view of stress corrosion cracking scc and corrosion fatigue cracking. Stress corrosion cracking behavior of nickel base alloys. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. Stainless steel types 304 and 316 can be considered resistant below 80 degc, up to the limit of solubility. A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. Improved resistance to caustic stress corrosion cracking can be given to inconel by heat treating it at 620 o c to 705 o c, depending upon prior solution treating temperature.
The stress corrosion cracking in expanded parts of stainless steel heat exchangers and its prevention were studied. Intergranular and transgranular stress corrosion cracking of the aisi 316l stainless steel at polythionic acid environment 8. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. Structural failure due to scc can be very unpredictablefailure could occur after as little as a few hours of exposure, or the equipment could continue to function normally for. Transgranular stress corrosion cracking an overview. Stresscorrosioncracking view from the penthouse the dnfm. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. Austenitic stainless steels and other low nickel materials may experience stress corrosion cracking or general corrosion in hot caustic soda. No evidence of caustic cracking was found in the stress corrosion tests for any.
Consequently, caustic corrosion called caustic embrittlement more accurately, a specific kind of stress corrosion cracking was engendered on the carbon steel tubes under both concentrated naoh and tensile stress because the operational pressure of the tube side was larger than the shell side, and corrosion products including na 3 feo 3, na. Stress corrosion cracking of stainless steel components in steam. Pdf stress corrosion cracking of stainless steel components in. Stress corrosion cracking of 316 stainless steel in.
Nov 11, 2018 this explains the stress corrosion and the conditions. Stress corrosion cracking of duplex stainless steels in caustic solutions. Stress corrosion cracking the international institute of. The mechanism of scc is shown as a simple representation in figure 1. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides. Model test blocks of the exchangers were constructed with tubes expanded by. The area of risk in sodium hydroxide is shown on the isocorrosion diagram by the area bounded by a. Although stainless is very durable, it is possible to abuse and damage it beyond reasonable repair. Caustic stress corrosion cracking occurs at higher temperatures than chloride stress corrosion cracking which can occur at temperatures as low as 60 degc. Corrosionpedia what is stress corrosion cracking scc. Stress corrosion cracking caustic embrittlement of super. Caustic stress corrosion cracking is a form of degradation that is caused when a. Stress corrosion cracking of 304l stainless steel in sodium. The stress corrosion cracking of type 316 stainless steel has been examined using both circumferentially notched 316 specimens and unnotched 9cr1mo to 316 transition joint samples, both tested in sodium hydroxide solutions at 300 or 350c.
S by means of potentiostatically controlled slow strain rate testing techniques ssrt. In this chapter, the conditions for the occurrence of scc are first introduced. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Selection stainless steel for handling sodium hydroxide naoh. In many ways, caustic scc of stainless steel represents a forgotten phenomenon, since it was researched, studied and quantified in. These alloys can however suffer from caustic stress corrosion cracking at caustic concentrations above 70% at temperatures above 290crmo c 550f. This explains the stress corrosion and the conditions. It is one of the most prevalent afflictions in the industry and one of many environmental cracking mechanisms that typically occur in carbon steel equipment, but it can also afflict low alloy and austenitic stainless steel equipment. Avoiding caustic stress corrosion cracking of carbon steel refinery equipment and piping this standard practice establishes guidelines to avoid caustic scc of cs refinery equipment and piping.
Caustic corrosion an overview sciencedirect topics. Stress corrosion cracking scc tests were conducted by the slow strain. Oct 20, 2019 the exposure temperature is a key parameter in the performance of type 316l stainless steel in caustic environments, affecting the length of the passive domain and corrosion rate. Chloride stress corrosion cracking inspectioneering. Risk of stress corrosion cracking attack caustic stress corrosion cracking occurs at higher temperatures than chloride stress corrosion cracking which can occur at temperatures as low as 60 degc. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. Pdf stress corrosion cracking of stainless steel components. As with other forms of stress corrosion cracking, caustic cracking will. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Stress corrosion cracking of type 304l stainless steel in.
The paper discusses stress corrosion cracking scc of stainless steel components due to the ingress of caustic into steam systems. In these media, many stainless steel grades suffer from crevice corrosion, pitting corrosion and stress corrosion cracking. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Corrosion of this type has been extensively studied and affects almost all metal alloys, including the. Stress corrosion cracking of type 304l stainless steel in sodium sulfidecontaining caustic solutions article in corrosion houston tx 5910. Similarly other specific stress corrosion cracking processes have acquired their own names. Stainless steel is perceived as the ultimate in bulletproof, easytosanitize equipment, and many home brewers aspire to the goal of an all stainless steel home brewery. Corrosion of stainless steel by hot caustic research using solutions of chemically pure caustic sodium hydroxide naoh led to the development of a diagram that attempts to delineate the param eters of concentration and tem perature governing stress corrosion cracking scc of type. Stress corrosion cracking of an austenitic stainless steel in. However, when sulfides are present in caustic solutions the scc of austenitic ss has been reported to occur at lower temperatures. Specialized corrosion doehdbk1015193 corrosion ch02 rev. The combination of tensile stress and a specific corrosive environment can crack stainless steels.
Which alloy material is most resistant to caustic soda. Microstructural changes during fabrication processes affect the overall scc susceptibility of these steels in caustic solutions. Although stress corrosion cracking of duplex stainless steels in chloride solution has been investigated and well documented in the literature but the scc mechanisms for dss in caustic solutions were not known. Stress corrosion cracking of type 316 stainless steel in. Selection of stainless steels for handling sodium hydroxide. Stresscorrosioncracking view from the penthouse the.
Stress corrosion cracking of an austenitic stainless steel. The environments used were deoxygenated 50% naoh sol. The use of austenitic stainless steel should be kept to a minimum. Caustic stress corrosion cracking inspectioneering. Stress corrosion cracking of 304l stainless steel in sodium sulfide. Abstract the paper discusses stress corrosion cracking scc of stainless steel components due to the ingress of caustic into steam systems.
Both 304 and 316 stainless steel types are resistant to a wide range of caustic stress corrosion cracking occurs at higher temperatures than chloride stress. The chief applications of hastelloy alloys are in the presence of hot chloride solutions. Ricker, national institute of standards and technology stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Chloride stress corrosion cracking in austenitic stainless. Stress corrosion cracking of stainless steel components in. Stress corrosion cracking of 304l stainless steel in. Alloy 400 n04400 and alloy 600 n06600 also have excellent stress corrosion resistance. Nace sp0403 avoiding caustic stress corrosion cracking. Industrial experience on the caustic cracking of stainless. For example, caustic crack propagation rate of a steel was reported 5,6 to be 25 times greater in a 3.
Caustic cracking can occur in carbon steel piping and equipment handling. Chloride stress corrosion cracking in austenitic stainless steel. The useful safe limit of carbon steel is approximately 150of65oc, both with re. This mode of attack is termed stress corrosion cracking scc. Austenitic stainless steels ss are known to be susceptible to caustic stress corrosion cracking scc at temperatures higher than. Austenitic stainless steels are known to be susceptible to caustic stress corrosion cracking scc above approximately 121c. Caustic cracking is a form of stress corrosion cracking most frequently encountered in carbon steels or ironchromiumnickel alloys that are exposed to concentrated hydroxide solutions at temperatures of 482f 250c.